8 tasks in organic chemistry (k / p 1, version 18)

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Uploaded: 08.10.2012
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1. For 3-methylpentene-1 write Scheme: a) mild oxidation (by Wagner); b) hydrochlorination; c) dehydrogenation. What happens under the action of a product of the latter reaction with sodium amide in liquid ammonia?
2. Write the intermediate and final products in the following diagram:
2-chlorobutyl-2 ---  A ----------  In ----  With ----------  D -----  E
Cat spirt.r-p-p spirt.r
What are the compounds of the systematic nomenclature.
3.Privedite circuit and corresponding reaction equations of the synthesis of the tertiary alcohol 3-methyl pentanol-1. Write for the resulting alcohol reaction: a) POCl3; b) metallic sodium.
4.Napishite reaction equations corresponding to the following scheme:
ethylene oxide H2O O
benzilmagniybromid -----------------  A -----  In ----  With
Bring the product to last the reactions with: a) chlorine in alkaline medium; b) hydrocyanic acid. Disassemble the mechanism of the reaction of the product C with hydrocyanic acid.
5. To carry out a series of isopropyl alcohol chain of reactions: a) dehydration; b) with phosphorus pentachloride; c) with an alcoholic solution of alkali; g) hydration; d) oxidation. What are the connections for the systematic nomenclature.
6.Sinteziruyte methyl phenyl, and propilfenilovy izopropilfenilovy esters. Give an appropriate reaction equations.
7.Sinteziruyte two ways propilpropanoat and phenyl ether ben zoate. Write the corresponding equations of reactions.
8.Napishite reaction equations corresponding to the following scheme:
KCN H2O, H + Cl2 + PCl3 PCl5
1-chloro-2-methyl propane -----  A --------  In ----------  With -----  D
Call intermediate and final compounds.

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